Get a flammable substance between its LEL and UEL. (ie mix in some air or oxygen). Provide the minimum ignition energy, or heat it up higher then its autoignition temperature. And boom. Simple. Good picks are gases and dusts. Methane explosions have killed dozens of people over the last year in my country alone.
The numbers can be found on google for most common substances.
Explosives also work, but thats what they are supposed to do.



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